Product ID:T 81772 TYPE 2 7652078 SOLVENT BLEND
MSDS Date:01/26/1998
FSC:8010
NIIN:01-200-2637
Status Code:A
MSDS Number: CLQXR

ASHLAND CHEMICAL CO DIV OF ASHLAND OIL INC

3849 FISHER RD
COLUMBUS, OH 43216
US

Emergency Phone: 1-800-274-5263

Info Phone: 614-790-3333 / 800-325-3751

Preparer: HENRY SIMMONS

Cage: 7L600

ASHLAND CHEMICAL CO DIV OF ASHLAND OIL INC

2219 COLUMBUS, OH 43216 US

Telephone: 614-790-3333 / 800-325-3751

Cage: 7L600

PROPYLENE GYLCOL MONOMETHYL ETHER

CAS: 107-98-2

RTECS: UB7700000

ACGIH TLV: 369 MG/M3;100 PPM

METHYL ISOBUTYL KETONE

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 410 MG/M3;100 PPM

ACGIH TLV: 205 MG/M3;50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ETHYL KETONE

CAS: 78-93-3

RTECS: EL6475000

OSHA PEL 590 MG/M3;200 PPM

ACGIH TLV: 590 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:EYE: CAN CAUSE EYE IRRITATION.
SYMPTOMS INCLUDE STINGING, TEARING, REDNESS, AND SWELLING OF EYES.
SKIN: CAN CAUSE SKIN IRRITATION. PROLONGED OR REPEATED CONTACT MAY
DRY THE SKIN. SYMPTOMS MAY INCLUDE REDNESS, BURNING, AND DRYING OF
SKIN, BURNS AND OTHER SKIN DAMAGE. SWALLOWING: SWALLOWING SMALL
AMOUNTS OF THIS MATERIAL DURING NORMAL HANDLING IS NOT LIKELY TO
CAUSE HARMFUL EFFECTS. SWALLOWING LAR GE AMOUNTS MAY BE HARMFUL.
INHALATION: BREATHING OF VAPOR OR MIST IS POSSIBLE. BREATHING SMALL
AMOUNTS OF THIS MATERIAL DURING NORMAL HANDLING IS NOT LIKELY TO
CAUSE HARMFUL EFFECT. BREATHING LARGE A MOUNTS MAY BE HARMFUL
Effects of Overexposure:SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL
THROUGH BREATHING, SWALLOWING, AND/OR PASSAGE OF THIS MATERIAL
THROUGH THE SKIN MAY INCLUDE: MOUTH AND THROAT IRRITATION
(SORENESS, DRY OR SCRATCHING FE ELING, COUGH), STOMACH OR
INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA), IRRITATION (NOSE,
THROAT, AIRWAYS), LUNG IRRITATION, CENTRAL NERVOUS SYSTEM
DEPRESSION (DIZZINESS, DROWSINESS, WEAKNESS, FATIGU E, HEADACHE,
UNCONSCIOUSNESS).

First Aid:EYES: IF SYMPTOMS DEVELOP, IMMEDIATELY MOVE INDIVIDUAL AWAY
FROM EXPOSURE AND INTO FRESH AIR. FLUSH EYES GENTLY WITH WATER FOR
AT LEAST 15 MINUTES WHILE HOLDING EYELIDS APART; SEEK IMMEDIATE
MEDICAL A TTENTION. SKIN; REMOVE CONTAMINATED CLOTHING. FLUSH
EXPOSED AREA WITH LARGE AMOUNTS OF WATER. IF SKIN IS DAMAGED, SEEK
IMMEDIATE MEDICAL CONDITION. SWALLOWING: SEEK MEDICAL ATTENTION.
IF INDIVIDUAL OR DROWSY OR UNCONSCIOUS, DO NOT GIVE ANYTHING BY
MOUTH; PLACE INDIVIDUAL ON THE LEFT SIDE WITH HEAD ONE.
INHALATION: IF SYMPTOMS DEVELOP, IMMEDIATELY MOVE INDIVIDUAL AWAY
FROM EXPOSURE AND INTO FRES H. SEEK IMMEDIATE MEDICAL CONDITION.

Flash Point Method:TCC
Flash Point:=-6.5C, 20.F
22-99F-6.6-37.2C
Lower Limits:1.4
Extinguishing Media:REGULAR FOAM, WATER FOG, CARBON DIOXIDE, DRY
CHEMICAL.
Fire Fighting Procedures:WEAR A SELF CONTAINED BREATHING APPARATUS WITH
A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WITH
APPROPRIATE TURNOUT GEAR AND CHEMICAL RESISTANT PROTECTIVE
EQUIPMENT. REFER TO THE PE RSONAL PROTECTIVE EQUIPMENT SECTION OF
THIS MSDS.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG THE GROUND OR MAY BE MOVED BY VENTILATION AND IGNITED
BY PILOT LIGHTS, OTHER FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC
MOTORS, STATIC DISCHARGE OR OTH ER IGNITION SOURCES AT LOCATION
DISTANT FROM MATERIAL HANDLING POINT.

Spill Release Procedures:SMALL SPILL - ABSORB LIQUID ON VERMICULITE,
FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. LARGE SPILL -
ELIMINATE ALL IGNITION SOURCES (FLARES, FLAMES INCLUDING PILOT
LIGHTS, ELECTRICAL SPARKS) PERSONS NOT WEARING PROTECTIVE
EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS
BEEN COMPLETED. STOP SPILL AT SOURCE. PREVENT FROM ENTERING DRAINS,
SEWERS, STREAMS OR OTHER BODIES OF WATER.

Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS PRODUCT RESIDUES
(VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THE
DATA SHEET MUST BE OBSERVED. ALL FIRE-GALLON PAILS AND LARGER
METAL CONTAINER, INCLUDING TANK CARS AND TANK TRUCKS.

Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT (S) OF PRODUCT OR
ANY COMPONENT IS EXCEEDED (SEE EXPOSURE GUIDELINES) A NIOSH/MSHA
APPROVES AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER
ENVIRONMENTAL CONTROL. O SHA REGULATIONS ALSO PERMIT OTHER
NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED
CONDITIONS (SEE YOUR INDUSTRIAL HYGIENIST).
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT
SUPPLIER)
Eye Protection:CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA
REGULATIONS ARE ADVISED.
Supplemental Safety and Health

Boiling Pt:=79.4C, 175.F
Vapor Pres:78 MMHG @ 68F
Spec Gravity:> 1.000
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:HOMOGENEOUS SOLUTION LIQUID
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:MAY FORM: CARBON DIOXIDE AND CARBON
MONOXIDE, VARIOUS HYDROCARBONS

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE, AND FEDERAL REGULATIONS

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:SARA 302 COMPONENTS - 40 CFR 355 APPENDIX A
NONE SECTION 311/312 HAZARD CLASS ? 40 CFR 370.2 IMMEDIATE
DELAYED FIRE SARA 313 COMPONENTS - 40 CFR 372.65 METHYL ETHYL
KETONE 78-93-3 52% METHYL ISOBUTYL KETONE 108-10-1 17%
Federal Regulatory Information:TSCA (UNITED STATES) THE INTENTION OF
THIS PRODUCT ARE LISTED CERCLA RQ ? 40 CFR 302.4 (A) METHYL ETHYL
KETONE 5000 LBS METHYL ISOBUTYL KETONE 5000 LBS
State Regulatory Information:CALIFORNIA PROPOSITION 65 NONE NEW JERSEY
RTK LABEL INFORMATION METHYL ETHYL KETONE 78-93-3 PROPYLENE
GLYCOL MONOMETHYL ETHER 107-98-2 METHYL ISOBUTYL KETONE 108-10-1
PENNSYLVANIA RTK LABEL INFOR MATION 2- BUTANONE 78-93-3 2-
PROPANOL, 1- METHOXY 107-98-2 2- PENTANONE, 4- METHYL 108-10-1